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Beyond Iron Trifluoride: A Matrix-Isolation and Quantum-Chemical Investigation of FeF₄

Tobias Schlöder, Thomas Vent-Schmidt, Sebastian Riedel— 2012

Beyond iron trifluoride: Matrix-isolation IR spectroscopy and state-of-the-art quantum-chemical calculations have led to the characterization of iron tetrafluoride, a previously unknown species. FeF4 has been prepared by co-deposition of laser-ablated iron atoms with fluorine under excess of noble gases (neon and argon) at cryogenic temperatures.

TitelBeyond Iron Trifluoride: A Matrix-Isolation and Quantum-Chemical Investigation of FeF₄
VerfasserTobias Schlöder, Thomas Vent-Schmidt, Sebastian Riedel
Datum2012
Kennung10.1002/anie.201206464
Quelle/n
Erschienen inAngew. Chem. Int. Ed. 2012, 51, 12063–12067 (Angew. Chem. 2012, 124, 12229–12233)
Spracheeng
ArtText