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A Matrix-Isolation and Quantum-Chemical Investigation of FeF4

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Tobias Schlöder, Thomas Vent-Schmidt, Sebastian Riedel – 2012

Beyond iron trifluoride: Matrix-isolation IR spectroscopy and state-of-the-art quantum-chemical calculations have led to the characterization of iron tetrafluoride, a previously unknown species. FeF₄ has been prepared by co-deposition of laser-ablated iron atoms with fluorine under excess of noble gases (neon and argon) at cryogenic temperatures.

Titel
A Matrix-Isolation and Quantum-Chemical Investigation of FeF4
Verfasser
Tobias Schlöder, Thomas Vent-Schmidt, Sebastian Riedel
Datum
2012
Erschienen in
Angew. Chem. Int. Ed. 2012, 51, 48, 12063–12067 Angew. Chem. 2012, 124, 48, 12229–12233
Zitierweise
DOI: 10.1002/anie.201206464 DOI: 10.1002/ange.201206464
Sprache
eng