The Reaction of White Phosphorus with NO+/NO2+[Al(ORF)4]−: The [P4NO]+ Cluster Formed by an Unexpected Nitrosonium Insertion
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Tobias Koechner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing – 2010
An appealing couple: The unprecedented insertion of the nitrosonium cation into a tetrahedral edge of white phosphorus forms the highly reactive [P₄NO]⁺ cation (see picture). The synthesis, characterization, and applications are discussed, and NO₂[Al(OC(CF₃)₃)₄] is presented as an easily synthesized oxidant.
Titel
The Reaction of White Phosphorus with NO+/NO2+[Al(ORF)4]−: The [P4NO]+ Cluster Formed by an Unexpected Nitrosonium Insertion
Verfasser
Tobias Koechner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing
Datum
2010
Erschienen in
Angew. Chem. Int. Ed. 2010, 49, 44, 8139-8143
Angew. Chem. 2010, 122, 44, 8316–8320
Zitierweise
DOI: 10.1002/anie.201003031
DOI: 10.1002/ange.201003031
Sprache
eng